Germanium-based materials with extremely high theoretical energy capacities have gained a lot of attention recently as potential anodes for lithium ion batteries. These materials can also offer improved Li in. Lithium ion batteries (LIBs) with advanced properties, such as high energy and power. Key challenges for successful improvement of future batteries lie in achieving high energy density and capacity, excellent rate capacity, long stable cycling life, low cost, environmental fri. Germanium-based compounds, including oxides, chalcogenides, phosphides, and germanates, followed the conversion and alloying reaction mechanism. The formation of new lithium oxi. Ge alloys and their composites undergo a stepwise lithiation/delithiation process, which favors the suppression of huge volume variations and brings a moderate operating voltage. Germanium-based anode materials possess high theoretical capacity, high intrinsic electronic conductivity and fast lithium ion diffusion kinetics, making it ideal anode materials t.
[PDF Version]
Are germanium-based materials a potential anode for lithium ion batteries?
Germanium-based materials with extremely high theoretical energy capacities have gained a lot of attention recently as potential anodes for lithium ion batteries.
Are germanium oxides a good raw material for lithium ion batteries?
The germanium oxides as raw material for the manufacturing of negative electrodes of lithium-ion and sodium-ion batteries are likely to take leading positions because they simplify technology of the electrodes' production and reduce their price significantly.
How much germanium does a lithium ion battery produce a year?
The annual world output of germanium does not exceed 130 t. In spite of the basic limitations, studies of the germanium applying in lithium-ion and sodium-ion batteries are continued on a large scale, which is confirmed, in particular, by the recent publishing of review-articles [25, 26, 37 – 47].
Is germanium a negative-electrode material in a lithium-ion battery?
Generally, this corresponds to the phase equilibrium diagrams [2, 3]. Germanium was first mentioned as a negative-electrode material in a traditional low-temperature lithium-ion battery in 2004 and 2008 [4 – 8]. In the quoted papers, the above-given composition of the lithium–germanium intermetallic compounds was largely confirmed.
How can germanium materials improve the electrochemical performance of a battery?
The preparation of germanium materials into nanoparticles, , nanowires, , nanotubes, , or nanofilms structures can significantly increase their specific surface area and lithium ion diffusion rate, thus improving the electrochemical performance of the battery.
Is germagraphene a promising anode material for lithium-ion batteries?
Hu, J., Ouyang, C., Yang, S.A., and Yang, H.Y., Germagraphene as a promising anode material for lithium-ion batteries predicted from first-principles calculations, Nanoscale Horiz., 2019, vol. 4, p. 457.